By Mohamed S. El-Aasser (auth.), Françoise Candau, Ronald H. Ottewill (eds.)
The progress of curiosity within the topic of Polymer Colloids over the past twenty 5 years or so has been very huge ensuing now in significant foreign meetings on an annual foundation and lots of nationwide ones besides. The curiosity stems not just from the wide variety of functions of those fabrics but additionally from a interest as to the mechanism of formation and their transforming into use as version debris to enquire primary points of physics and chemistry. In July 1988 a NATO complex examine Institute used to be held in Strasbourg, France, on the Centre St. Thomas. As a tutorial creation to this I nstitute a chain of 8 lectures used to be given to hide the elemental features of the topic. those 8 lectures have now been compiled into an Introductory textual content protecting, emulsion poly merization, dispersion polymerization, inverse emulsion polymerization, the morphology of copolymer latices, the colloidal homes of latices, characterization equipment and rheology. it really is was hoping that those will serve a large viewers, undergraduates, graduate-students and examine employees, either in and academe. The chapters all include evaluate fabric modern on the time of e-book. fhe 1988 NATO complex learn I nstitute was once made attainable through a supply from the NATO-AS I programme and the subsequent businesses: BASF, Ludwigshafen, West Germany The Dow Chemical corporation, Michigan, united states Dow Chemical Rheinwerk GmbH, Rheinmunster, West Germany ICI PLC, Runcorn, England S. C. Johnson and Son Inc., Racine, united states NORSOLOR, Verneuil en Halatte, France Rhone Poulenc, Aubervilliers, France.
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Extra info for An Introduction to Polymer Colloids
Consequently, the coagulation rate constant is high and independent of the surfactant concentration, which results in a relatively low number of particles. As the surfactant concentration is increased, the surface charge density increases rapidly, and the coagulation rate coefficient decreases, with the result more precursors grow by propagation to mature particles. With further increase in the surfactant concentration, a point is reached where the particle surface is now saturated and the surface charge density becomes independent of the surfactant concentration.
At low NaSS concentration, less than 1% based on monomer, the particle size decreased linearly with NaSS concentration and the distribution was narrow. This was explained by a homogeneous nucleation mechanism, where a large number of highly charged stable oligomeric radicals are formed in the aqueous phase, which are converted to primary growing particles. On the other hand, at higher NaSS concentration between 1-10% based on the monomer charge, the particle si ze showed a non linear relationship with the NaSS concentration and the 28 distribution became much broader with secondary particles together with a small number of oversize particles.
16. 17. 18. 19. 20. 21. 22. 23. in Industry", Consultants Bureau, New York, 1981. , New York, 1982. Marten, Land Hamielec, A. Series, 1979, 104, 43. W. H. W. 67, M. Nijhoff, The Hague, 1983, 140. C. , 1982, 20, 1299;1315;1330;1345. H. Reichert, and W. Geisler, Huthig and Wepf, Heidelberg, 1986, 275. J. , Macromolecules, 1981, 14, 1501; 1982, 459. , 1947, ~ 217. , 1948, l§. (6),592. , 1968, ~ 20. , 1963, g, 741. , in Vinyl Polymerization II, Ed. E. Ham, Dekker, New York, 1969, 210. E. , 1965, ~ 156.
An Introduction to Polymer Colloids by Mohamed S. El-Aasser (auth.), Françoise Candau, Ronald H. Ottewill (eds.)